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以下是北京化工大学化学工程与技术专业研究生导师介绍咨询QQ、微信:2544906的可控运动及超分子组装”这一研究主题,在国内较早开展了基于微米以上尺度构筑基元的超分子组装及其扩散过程的研究。针对宏观超分子组装由构筑基元的“扩散运动”与“组装过程”构成的特点,我们提出了“宏观构筑基元的可控运动是实现其超分子组装的先决条件”和“引入柔性间隔层是实现宏观构筑基元间超分子相互作用的重要设计原则”的学术观点,相关成果已在Adv. Mater.、Angew. Chem. Int. Ed.、Adv. Funct. Mater.、NPG Aisa Mater.、Small、J. Mater. Chem.等材料领域国际知名期刊发表论文59篇(其中独立工作后发表39篇);论文被SCI他引2745次(近五年1917次)。 作为负责人主持国家自然科学基金项目3项;获得2015年教育部青年长江学者,2014年国家自然科学基金委优秀青年基金,教育部新世纪人才项目,教育部霍英东基金,北京市新星计划,北京市教委共建项目,教育部科学技术重点项目,教育部留学归国人员启动基金,北京市青年英才计划各一项;中央直属高校基本科研业务费项目两项;参加国家自然科学基金群体创新项目一项。 1. 宏观尺度构筑基元的扩散过程咨询QQ、微信:2544906运动、相互碰撞,发生组装;然而,当组装基元的尺度到10微米以上时,分子热运动已经不能有效驱使构筑基元运动使其发生碰撞和组装。因此我们提出了“宏观尺度构筑基元的可控运动是实现其组装的关键性因素”的观点。围绕这一关键科学问题,我们通过磁场、化学反应等多种途径驱使宏观尺度构筑基元进行可控运动,使其到达能够发生超分子相互作用的位点,实现了表面二维有序结构的可控组装,为发展功能性自组装三维结构提供了新方法(Adv. Mater. 2010, 22, 5125;2013, 25, 2915;2014, 26, 306; 2014, 26, 7059; Adv. Funct. Mater. 2015, 25, 5786; 2015, Accepted; NPG Asia Mater. 2014, 6, e111; 2014, 6, e128; Small 2013, 9, 2509; 2014, 10, 859; 2014, 10, 3907; 2015, 11,1665.)。 2. 宏观尺度构筑基元表面修饰与组装咨询QQ、微信:2544906的尺寸和表面效应所导致的难以组装问题,从而实现宏观尺度的超分子组装,我们提出了“柔性间隔层”的概念并实现了构筑基元间的选择性组装;通过在体系中引入高结合常数的竞争性客体分子可实现其解组装,从而证实柔性间隔层在宏观超分子组装中通过多重相互作用实现组装的机理(Adv. Mater. 2014, 26, 3009; Angew. Chem. Int. Ed. 2015, 54, 8952; Adv. Funct. Mater. 2015, ASAP, DOI: 10.1002/adfm.201503366; ACS. Appl. Mater. Interfaces 2014, 6, 7572; Small 2014, 10, 3907; Langmuir 2011, 27, 6559.)。在表面修饰方面,我们率先采用化工过程强化的手段研究聚合物多层膜的扩散过程,有效提高了聚合物多层膜的组装效率和成膜质量(Langmuir 2012, 28, 9849; J. Mater. Chem. A 2014, 2, 14048; ACS. Appl. Mater. Interfaces 2015, 7, 18824; Soft Matter 2015, 11, 5748);提出了后渗透双官能度可光交联小分子的方法实现了多种聚合物多层膜的稳定(Langmuir 2012, 28, 7096; J. Mater. Chem. A 2013, 1, 11329; ACS Appl. Mater. Interfaces 2013, 5, 8308; RSC Adv. 2014, 4, 5683; J. Mater. Chem. B 2015, 3, 562)。 奖励与荣誉: 2004年获得吉林大学唐敖庆奖学金; 2007年获得清华大学优秀博士论文一等奖,清华大学航天海鹰杯学术新秀; 2008年获得教育部百篇优秀博士论文提名奖; 2009年获得北京市科技新星计划资助; 2010年获得教育部新世纪优秀人才支持计划资助; 2012年获得教育部霍英东基金资助; 2013年获得北京市青年英才计划资助; 2014年获得优秀青年基金; 2015年获得教育部青年长江学者。 代表性论文: 1. Converting chemical energy into electricity through a functionally cooperating device with diving-surfacing cycles. Adv. Mater. 2014, 26, 7059-7063. Mengmeng Song, Mengjiao Cheng, Guannan Ju, Yajun Zhang, Feng Shi* 2. Macroscopic supramolecular assembly of rigid building blocks through a flexible spacing coating. Adv. Mater. 2014, 26, 3009-3013. Mengjiao Cheng, Feng Shi*, Jianshu Li, Zaifu Lin, Chao Jiang, Meng Xiao, Liqun Zhang, Wantai Yang*, Toshio Nishi 3. Bell-shaped superhydrophilic-superhydrophobic-superhydrophilic double transformation on a pH-responsive smart surface. Adv. Mater. 2014, 26, 306-310. Mengjiao Cheng, Qian Liu, Guannan Ju, Yajun Zhang, Lei Jiang, Feng Shi* 4. Smart transportation between three phases through a stimulus-responsive functional cooperating device. Adv. Mater. 2013, 25, 2915-2919. Guannan Ju, Mengjiao Cheng, Meng Xiao, Jianmei Xu, Kai Pan, Yajun Zhang,* Feng Shi* 5. Diving–surfacing cycle within a stimulus-responsive smart device towards developing functionally cooperating systems. Adv. Mater. 2010, 22, 5125-5128 Yongfeng Gao, Mengjiao Cheng, Baoling Wang, Zeguo Feng, Feng Shi* 6. Precise macroscopic supramolecular assembly by combining spontaneous locomotion driven by the marangoni effect and molecular recognition. Angew. Chem. Int. Ed. 2015, 54, 8952-8956. Meng Xiao, Yiming Xian, Feng Shi* 7. Diving-surfacing smart locomotion driven by the co2-forming reaction and its application on mini-generator. Adv. Funct. Mater. 2015, Accepted. Lina Zhang, Mengmeng Song, Meng Xiao, Feng Shi* 8. Macroscopic supramolecular assembly to fabricate 3D ordered structures: towards potential tissue scaffolds with targeted modification. Adv. Funct. Mater. 2015, ASAP, DOI: 10.1002/adfm.201503366. Mengjiao Cheng, Yue Wang, Lingling Yu, Haijia Su, Weidong Han,* Zaifu Lin, Jianshu Li, Haojie Hao, Chuan Tong, Xiaolei Li, Feng Shi* 9. pH-Responsive round-way motions of a smart device through integrating two types of chemical actuator in one smart system. Adv. Funct. Mater. 2015, 25, 5786-5793. Lingling Yu, Mengjiao Cheng, Mengmeng Song, Dequn Zhang, Meng Xiao, Feng Shi* 10. Design of UV-responsive micro-actuator on smart device towards light induced on-off-on motion. NPG Asia Mater. 2014, 6, e128. Meng Xiao, Chao Jiang, Feng Shi* 11. A pH-responsive smart surface for the continuous separation of oil/water/oil ternary mixtures. NPG Asia Mater. 2014, 6, e111. Guannan Ju, Mengjiao Cheng, Feng Shi* 12. Surface adhesive force: a metric describing the drag-reducing effects of superhydrophobic coatings. Small 2015, 11, 1665-1671. Mengjiao Cheng, Mengmeng Song, Hongyu Dong, Feng Shi* 13. Supramolecular assembly of macroscopic building blocks through self-propelled locomotion by dissipating chemical energy. Small 2014, 10, 3907-3911. Mengjiao Cheng, Guannan Ju, Yingwei Zhang, Mengmeng Song, Yajun Zhang, Feng Shi* 14. pH-Responsive on-off motion of a superhydrophobic boat: towards the design of a minirobot. Small 2014, 10, 859-865. Meng Xiao, Xianpeng Guo, Mengjiao Cheng, Guannan Ju, Yajun Zhang, Feng Shi* 15. Combining the marangoni effect and the ph-responsive superhydrophobicity–superhydrophilicity transition to biomimic the locomotion process of the beetles of Genus Stenus. Small 2013, 9, 2509-2514. Meng Xiao, Mengjiao Cheng, Yajun Zhang*, Feng Shi* [/td] [/tr] [tr] [td=4,1]◇ 本人从事的主要研究方向:[/td] [/tr] [tr] [td=4,1]超分子组装[/td] [/tr] [tr] [td=4,1,100%] ◇ :在国内外核心期刊上发表学术论文情况 | 论文题目 | 刊物名称 | 刊物国家 | 收录情况 | 卷期 | 排名 | Converting chemical energy into electricity through a functionally cooperating device with diving-surfacing cycles | Adv. Mater. | 国外 | SCI | 2014, 26, 7059-7063 | 通讯 | Macroscopic supramolecular assembly of rigid building blocks through a flexible spacing coating | Adv. Mater. | 国外 | SCI | 2014, 26, 3009-3013 | 通讯 | Bell-shaped superhydrophilic-superhydrophobic-superhydrophilic double transformation on a pH-responsive smart surface | Adv. Mater. | 国外 | SCI | 2014, 26, 306-310 | 通讯 | Smart transportation between three phases through a stimulus-responsive functional cooperating device | Adv. Mater. | 国外 | SCI | 2013, 25, 2915-2919 | 通讯 | Diving–surfacing cycle within a stimulus-responsive smart device towards developing functionally cooperating systems | Adv. Mater | 国外 | SCI | 2010, 22, 5125-5128 | 通讯 | | [/td] [/tr] [/table] [/td] [/tr] [/table] [/td] [/tr] [/table] |
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